Reflectivity

Reflectivity refers to the measurement of the intensity of reflection off of a flat interface. The term both describes the physical phenomenon, as well as the experimental technique.

X-ray Reflectivity (XRR or XR) and neutron reflectivity (NR) are techniques which measure the intensity of reflected radiation as a function of angle (where, by definition for specular reflectivity, the incident and exit angles are equal; Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle \theta_i = \theta_f} ). A plot of reflectivity (R) versus angle yields the reflectivity curve. For XR and NR, the data is typically plotted as a function of the momentum transfer parallel to the film normal:

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle q_z = \frac{4\pi}{\lambda} \sin \theta_i }

Reflectivity calculation for a thin film.

Mathematical form

Ideal interface

In its simplest form, the Fresnel reflectivity can be given by:

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle r_F = \frac{k_z-\tilde{k}_z}{k_z+\tilde{k}_z} }

Where Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle k_z} is the vertical (z) component of the momentum of the incident wave, and Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle \tilde{k}_z} is the vertical component of the transmitted wave:

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \tilde{k}_z = - \sqrt{ n^2 k^2_0 - |k_{\parallel}|^2 } }

and n is the complex refractive index of the substrate. The reflected intensity (which is what is measured experimentally) is Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle R_F = |r_f|^2} . Close to the critical angle (Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle \theta_i \approx \theta_c} ), the beam is strongly refracted and:

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \tilde{k}_z = k \sqrt{ \theta_i - \theta_c } }

Thus, when the incident angle is less than the critical angle (Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle \theta_i < \theta_c} ), the transmitted wave-vector is purely imaginary: \tilde{k}_z = i k \sqrt{ \theta_c - \theta_i } This corresponds to the wave being totally externally reflected (evanescent probing only). Above the critical angle, the reflected intensity falls off rapidly: Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle R_F \sim \theta_i^{-4}} (c.f. Fresnel plot).

Rough interface

A flat interface with a small amount of roughness can be modelled using idealized uncorrelated roughness, which is characterized by a mean standard deviation of the height Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle \sigma = \sqrt{ \left \langle h^2 \right \rangle }} :

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle r_S = r_F e^{ -2 \sigma^2 k_z \tilde{k}_z } }

For a substrate with a single continuous layer of thickness h (e.g. a uniform thin film), the reflectivity becomes:

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle r_S = \frac{ r_{01} + r_{12} e^{ 2i \tilde{k}^1_z h } }{ 1 + r_{01} r_{12} e^{ 2i \tilde{k}^1_z h } } }

where

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \tilde{k}^j_z = - \sqrt{ n^2_j k^2_0 - |k_{\parallel}|^2 }}

is the perpendicular component of the wave-vector (in medium j). The reflectivity coefficients are:

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle f_{ij} = \frac{ \tilde{k}^i_z - \tilde{k}^j_z }{ \tilde{k}^i_z + \tilde{k}^j_z } }

Where Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle r_{01}} and Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle r_{12}} for the vacuum-layer and layer-substrate interfaces, respectively. This is called the 'one-box model'.

Multiple interfaces: Parratt formalism

The reflectivity from a stack of different layers can be computed using the so-called Parratt recursion formalism, which accounts for the effect of reflection from each internal interface, including their coherent interference to yield the final reflection intensity. This formalism can, in fact, be used to simulate or fit an arbitrary electron-density distribution (in the film-normal direction). Any continuous variation of density can be simulated by discretizing the system into a finite number of layers of finite thickness.

The Parratt formalism is recursive. The reflected and transmitted amplitude of layer j are given by Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle R_j} and Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle T_j} , such that:

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle X_j = \frac{R_j}{T_j} = e^{ - 2i k_{z,j} z_j } \frac{ r_{j,j+1} + X_{j+1} e^{2 i k_{z,j} z_j} }{ 1 + r_{j,j+1} X_{j+1} e^{2 i k_{z,j} z_j} } }

where

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle r_{j,j+1} = \frac{ k_{z,j} - k_{z,j+1} }{ k_{z,j} + k_{z,j+1} } }

is the Fresnel coefficient for interface Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle j} . The resultant system of equations can be solved by setting Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T_1 = 1} (i.e. the incident wave is normalized to unity) and Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle R_{N+1} = 0} (i.e. there is no reflection from the bottom of the substrate).

The interference between various reflections generically leads to oscillations in the reflectivity curve (so-called Kiessig fringes). A one-box model (uniform thin film on a substrate) will give rise to a set of fringes with a single periodicity, which is related to the film thickness h via Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \Delta q_z = 2 \pi / h} . Multiple layers of different thickness will give fringes of different periodicities, superimposed in the reflectivity curve. This can also give rise to beat-patterns in the curve. A multi-layer stack with a repeated thickness (e.g. alternating layers of two materials, always with the same thickness) will interfere constructively to give a strong peak at a q_z corresponding to the layering distance. This is called a Bragg peak, and can also be thought of as the Structure Factor of lamellar ordering.

There are many available software packages which implement the Parratt formalism. These packages can be used to fit experimental data, and thereby obtain a possible (thought not unambiguous) curve for the realspace average density (SLD) profile in the film-normal direction.

• L. G. Parratt Surface Studies of Solids by Total Reflection of X-Rays Phys. Rev. 1954, 95, 359. doi: 10.1103/PhysRev.95.359

Master-Formula

For sufficiently large incident angle (Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle \theta_i \gg \theta_c} ), a kinematical appoximation can be valid. In such a case, the electron-density profile Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle \rho_e(z)} can be described using the so-called Master-Formula:

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle R(q_z) = R_F \left| \frac{1}{\rho_e(z \to \infty)} \int \frac{\mathrm{d}\rho_e}{\mathrm{d}z} e^{i q_z z} \mathrm{d}z \right|^2 }

This formalism breaks down near the critical angle, but can be useful for predicting the reflectivity at higher angles, since the closed-form equation is simple to evaluate. It should be noted that this is essentially a Fourier transform of the density variation. In fact, this form highlights that the reflectivity comes from the variation of the material's refractive index (only points with non-zero Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathrm{d}\rho_e/\mathrm{d}z} contribute to the integral). This makes plain that the reflectivity comes from locations where the refractive-index changes abruptly (at interfaces), or gradually.

• P. Fenter, F. Schreiber, V. Bulovic, and S. R. Forrest Thermally induced failure mechanism of organic light emitting device structures probed by X-ray specular reflectivity Chem. Phys. Lett. 1997, 277, 521. doi: 10.1016/S0009-2614(97)00941-X
• I.W. Hamley and J.S. Pedersen Analysis of neutron and X-ray reflectivity. I. Theory J. Appl. Cryst. 1994, 27, 29-35. doi: 10.1107/S0021889893006260
• J. S. Pedersen and I. W. Hamley Analysis of neutron and X-ray reflectivity. II. Constrained least-squares methods J. Appl. Cryst. 1994, 27, 36-49. doi: 10.1107/S0021889893006272

Off-Specular Reflectivity

By definition, specular reflectivity involves setting the incident and detection angles to be equal, Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle \theta_i = \theta_f} . This inherently probes exactly along the q_z axis in reciprocal-space. One can also measure the off-specular reflectivity; i.e., the intensity of the reflectivity signal when the incident and exit angles are not quite equal. This can be accomplished either by holding the incident angle fixed, and rocking the point detector (or, equivalently, using a 1D detector); or this can be accomplished by holding the detector fixed and rocking the sample or input angle. In all cases, one is measuring the intensity in reciprocal-space near (but not exactly along) the q_z axis. Thus, off-specular reflectivity directly connects to other scattering geometries. E.g. the specular rod seen in GISAXS is off-specular reflectivity (in GI, the specular reflection is a single point on the reflectivity curve; data near this point is thus off-specular). Note that during a specular reflectivity scan, one may want to measure and subtract a background scan from the data. A typical way to obtain a background is to perform a corresponding scan with a small offset of the sample or detector. Thus, in specular reflectivity, the 'background' is actually an off-specular signal.

While the specular reflectivity (q_z axis) encodes information about the structure of the sample in the film-normal direction, the off-specular data encodes information about deviations from this idealized structure. I.e. it contains information about in-plane correlations/order. This may be as simple as probing the lengthscale of roughness, or even probing well-defined in-plane structures.

• R. M. Richardson, J. R. P. Webster and A. Zarbakhsh Study of Off-Specular Neutron Reflectivity Using a Model System J. Appl. Cryst. 1997, 30, 943-947. doi: 10.1107/S0021889897003440

References

Modeling

• Krassimir Stoev and Kenji Sakurai Recent theoretical models in grazing incidence x-ray reflectometry The Rigaku Journal 1997, 14, 22-37.

Data Fitting

• Nelson, A. Co-refinement of multiple contrast neutron / X-ray reflectivity data using MOTOFIT Journal of Applied Crystallography 2006, 39, 273-276. doi: 10.1107/S0021889806005073
• Charles F. Laub and Tonya L. Kuhl Fitting a free-form scattering length density profile to reflectivity data using temperature-proportional quenching J. Chem. Phys. 2006, 125, 244702. doi: 10.1063/1.2403126
• A. van der Lee, F. Salah and B. Harzallah A comparison of modern data analysis methods for X-ray and neutron specular reflectivity data J. Appl. Cryst. 2007, 40, 820-833. doi: 10.1107/S0021889807032207
• S. M. Danauskas, D. Li, M. Meron, B. Lin and K. Y. C. Lee Stochastic fitting of specular X-ray reflectivity data using StochFit J. Appl. Cryst. 2008, 41, 1187-1193. doi: 10.1107/S0021889808032445

Reviews

• T.P. Russell X-ray and neutron reflectivity for the investigation of polymers Materials Science Reports 1990, 5 (4), 171–271. doi: 10.1016/S0920-2307(05)80002-7
• H. Zabel X-ray and neutron reflectivity analysis of thin films and superlattices Applied Physics A 1994, 58 (3), 159-168. doi: 10.1007%2FBF00324371
• A. Gibaud, S. Hazra X-ray reflectivity and diffuse scattering Current Science 2000, 78 (12), 1467-1477.

See Also

• Reflectivity Software
• Fresnel plot
• Oscillations below the critical angle
• DWBA: A formalism for modeling GISAXS data, including reflection effects.
• Frank Schreiber, Alexander Gerlach X-Ray and Neutron Reflectivity for the Investigation of Thin Films – A Short Tutorial