Origin of the scattering lengths
The following description is adapted from Boualem Hammouda's (NCNR) SANS tutorial.
Consider first the energies of neutrons used in scattering experiments. A thermal neutron
, the energy for even a thermal neutron (1.8 Å wavelength) is
Consider a neutron of energy
interacting with a nucleus, which exhibits an attractive square well of depth
and width
; where
. The Schrödinger equation is:
![{\displaystyle \left[-{\frac {h^{2}}{8\pi ^{2}m}}\nabla ^{2}+V(r)\right]\psi (r)=E\psi (r)}](https://wikimedia.org/api/rest_v1/media/math/render/svg/fb9036866f37adb8069c1f1f0cded79812a811ac)
Outside of the square-well (
),
, and so the equation is solved as simply:

where
. Inside the square-well (
), the potential is
, and the solution becomes:

where
. The two solutions are subject to a continuity boundary condition at
:

Note that the mass of a neutron is ~10−27 kg
Note that
for , and