Absorption length

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Revision as of 14:47, 6 June 2014 by KevinYager (talk | contribs) (Calculating)
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The absorption length or attenuation length in x-ray scattering is the distance over which the x-ray beam is absorbed. By convention, the absorption length ϵ is defined as the distance into a material where the beam flux has dropped to 1/e of its incident flux.

Absorption

The absorption follows a simple Beer-Lambert law:

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{I(x)}{I_0} = e^{ - x / \epsilon } }

The attenuation coefficient (or absorption coefficient) is simply the inverse of the absorption length; Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mu = 1/\epsilon}

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{I(x)}{I_0} = e^{ - \mu x } }

Calculating

The absorption length arises from the imaginary part of the atomic scattering factor, f2. It is closely related to the absorption cross-section, and the mass absorption coefficient. Specifically, the atomic photoabsorption cross-section can be computed via:

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \sigma = 2 r_e \lambda f_2 }

Where λ is the x-ray wavelength, and re is the classical electron radius. The attenuation coefficient is given by:

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \begin{alignat}{2} \mu & = \frac{\rho N_a}{m_a} \sigma \\ & = \frac{\rho N_a}{m_a} \2 r_e \lambda f_2 \end{alignat} }

where ρ is density, Na is the Avogadro constant, and ma is the atomic molar mass. Note that the mass attenuation coefficient is simply Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mu/\rho} .

See Also