Absorption length

The absorption length or attenuation length in x-ray scattering is the distance over which the x-ray beam is absorbed. By convention, the absorption length ϵ is defined as the distance into a material where the beam flux has dropped to 1/e of its incident flux.

Absorption

The absorption follows a simple Beer-Lambert law:

${\frac {I(x)}{I_{0}}}=e^{-x/\epsilon }$

The attenuation coefficient (or absorption coefficient) is simply the inverse of the absorption length; $\mu =1/\epsilon$

${\frac {I(x)}{I_{0}}}=e^{-\mu x}$

Calculating

The absorption length arises from the imaginary part of the atomic scattering factor, f₂. It is closely related to the absorption cross-section, and the mass absorption coefficient. Specifically, the atomic photoabsorption cross-section can be computed via:

$\sigma =2r_{e}\lambda f_{2}$

Where λ is the x-ray wavelength, and r_e is the classical electron radius. The attenuation coefficient is given by:

${\begin{alignedat}{2}\mu &={\frac {\rho N_{a}}{m_{a}}}\sigma \\&={\frac {\rho N_{a}}{m_{a}}}2r_{e}\lambda f_{2}\end{alignedat}}$

where ρ is density, N_a is the Avogadro constant, and m_a is the atomic molar mass. Note that the mass attenuation coefficient is simply $\mu /\rho$.

Related forms

As can be seen, there are many related quantities which express the material's absorption:

• Absorption length $\epsilon$, the distance over which the intensity falls to 1/e.
• Attenuation coefficient Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mu} , the characteristic inverse-distance for attenuation.
• Mass attenuation coefficient Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mu/\rho} , the density-scaled attenuation.
• Absorptive atomic scattering factor Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle f_2} , the intrinsic dissipative interaction of the material.
• Atomic photoabsorption cross-section Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \sigma} , the cross-section ('effective size') of the atom's x-ray absorption (capture) efficiency.
• Imaginary refractive index Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \beta} , the resonant component of the refractive index.
• Imaginary Scattering Length Density Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathrm{Im}(\mathrm{SLD})} , the absorptive component of the scattering contrast.

Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon = \frac{1}{\mu}}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon = \frac{\rho}{\mu/\rho}}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon = \frac{m_a}{\rho N_a 2 r_e \lambda f_2 }}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon = \frac{m_a}{\rho N_a \sigma}}		Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon = \frac{m_a }{2 M_a \lambda \mathrm{Im}(\mathrm{SLD})} }
Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mu = \frac{1}{\epsilon}}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mu}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mu = \frac{\mu/\rho}{\rho}}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mu = \frac{\rho N_a}{m_a} 2 r_e \lambda f_2}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mu = \frac{\rho N_a}{m_a} \sigma}		Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mu = \frac{2 M_a \lambda}{m_a } \mathrm{Im}(\mathrm{SLD})}
Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{\mu}{\rho} = \frac{1}{\rho\epsilon}}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{\mu}{\rho} = \mu/\rho}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{\mu}{\rho}}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{\mu}{\rho} = \frac{N_a}{m_a} 2 r_e \lambda f_2}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{\mu}{\rho} = \frac{N_a}{m_a} \sigma}	${\frac {\mu }{\rho }}=$	${\frac {\mu }{\rho }}={\frac {2M_{a}\lambda }{\rho m_{a}}}\mathrm {Im} (\mathrm {SLD} )$
$f_{2}={\frac {m_{a}}{\rho N_{a}2r_{e}\lambda \epsilon }}$	Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle f_{2}={\frac {m_{a}}{\rho N_{a}2r_{e}\lambda }}\mu }	Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle f_{2}={\frac {m_{a}}{N_{a}2r_{e}\lambda }}{\frac {\mu }{\rho }}}	$f_{2}$	$f_{2}={\frac {\sigma }{2r_{e}\lambda }}$	$f_{2}={\frac {2\pi M_{a}}{\rho N_{a}r_{e}\lambda ^{2}}}\beta$	$f_{2}={\frac {M_{a}}{\rho N_{a}r_{e}}}\mathrm {Im} (\mathrm {SLD} )$
Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle \sigma ={\frac {m_{a}}{\rho N_{a}\epsilon }}}	$\sigma ={\frac {m_{a}}{\rho N_{a}}}\mu$	$\sigma ={\frac {m_{a}}{N_{a}}}{\frac {\mu }{\rho }}$	$\sigma =2r_{e}\lambda f_{2}$	$\sigma$	$\sigma ={\frac {4\pi M_{a}}{\rho N_{a}\lambda }}\beta$	$\sigma ={\frac {2\lambda M_{a}}{\rho N_{a}}}\mathrm {Im} (\mathrm {SLD} )$
			$\beta ={\frac {\rho N_{a}r_{e}\lambda ^{2}}{2\pi M_{a}}}f_{2}$	$\beta ={\frac {\rho N_{a}\lambda }{4\pi M_{a}}}\sigma$	$\beta$	$\beta ={\frac {\lambda ^{2}}{2\pi }}\mathrm {Im} (\mathrm {SLD} )$
Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle \mathrm {Im} (\mathrm {SLD} )={\frac {m_{a}}{2M_{a}\lambda \epsilon }}}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathrm{Im}(\mathrm{SLD}) = \frac{m_a }{2 M_a \lambda} \mu}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathrm{Im}(\mathrm{SLD}) = \frac{\rho m_a }{2 M_a \lambda} \frac{\mu}{\rho}}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathrm{Im}(\mathrm{SLD}) = \frac{\rho N_a r_e }{M_a} f_2}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathrm{Im}(\mathrm{SLD}) = \frac{\rho N_a}{2 \lambda M_a}\sigma}	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathrm{Im}(\mathrm{SLD}) = \frac{2 \pi \beta}{\lambda^2} }	Failed to parse (MathML with SVG or PNG fallback (recommended for modern browsers and accessibility tools): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathrm{Im}(\mathrm{SLD})}

See Also

• LBL X-Ray Attenuation Length calculator
• APS absorption calculator
• Wikipedia: Mass attenuation coefficient
• NIST tables of x-ray mass attenuation coefficient