Difference between revisions of "Example:Polymer clustering"
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Polymer solutions frequently exhibit some degree of clustering of the polymer chains. A more extreme case are hydrogels, where the polymer chains may be strongly-associated, or even crosslinked, into a network or mesh. | Polymer solutions frequently exhibit some degree of clustering of the polymer chains. A more extreme case are hydrogels, where the polymer chains may be strongly-associated, or even crosslinked, into a network or mesh. | ||
| − | Hammouda ''et al.'' proposed the following functional form to describe [[scattering]] | + | Hammouda ''et al.'' proposed the following functional form to describe [[scattering]] [[Scattering intensity|intensity]] from such systems: |
:<math> | :<math> | ||
I(q) = \frac{A}{q^n} + \frac{C}{1 + (q \xi)^m} + B | I(q) = \frac{A}{q^n} + \frac{C}{1 + (q \xi)^m} + B | ||
</math> | </math> | ||
| − | where ''B'' is a constant [[background]]. The first term represents the [[Porod scattering]] from clusters, while the second term is a Lorentzian function ascribed | + | where ''B'' is a constant [[background]]. The first term represents the [[Porod scattering]] from clusters, while the second term is a Lorentzian function ascribed to the scattering of the polymer chains themselves. In the context of a gel, <math>\scriptstyle \xi</math> represents the average mesh size. The parameters ''A'', ''C'', ''n'', and ''m'' may be used as fitting parameters. |
| + | |||
| + | [[Image:Gel scattering example.png|thumb|center|300px]] | ||
| + | |||
| + | ==Kratky plot== | ||
| + | In a [[Kratky plot]] (<math>\scriptstyle q^2I(q) </math> vs. <math>\scriptstyle q</math>), the equation becomes: | ||
| + | |||
| + | :<math> | ||
| + | q^2 I(q) = \frac{A}{q^{n-2}} + \frac{C q^2}{1 + (q \xi)^m} + B q^2 | ||
| + | </math> | ||
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* Boualem Hammouda, Derek L. Ho, and Steve Kline [http://pubs.acs.org/doi/abs/10.1021/ma049623d Insight into Clustering in Poly(ethylene oxide) Solutions] ''Macromolecules'' '''2004''', 37 (18), 6932-6937. [http://dx.doi.org/10.1021/ma049623d doi: 10.1021/ma049623d] | * Boualem Hammouda, Derek L. Ho, and Steve Kline [http://pubs.acs.org/doi/abs/10.1021/ma049623d Insight into Clustering in Poly(ethylene oxide) Solutions] ''Macromolecules'' '''2004''', 37 (18), 6932-6937. [http://dx.doi.org/10.1021/ma049623d doi: 10.1021/ma049623d] | ||
* S.R. Kline "[http://www.ncnr.nist.gov/programs/sans/pdf/publications/0569.pdf Reduction and Analysis of SANS and USANS Data using Igor Pro]", ''J. Appl. Cryst.'' 2006, 39, 6, 895. [http://dx.doi.org/10.1107/S0021889806035059 doi:10.1107/S0021889806035059] | * S.R. Kline "[http://www.ncnr.nist.gov/programs/sans/pdf/publications/0569.pdf Reduction and Analysis of SANS and USANS Data using Igor Pro]", ''J. Appl. Cryst.'' 2006, 39, 6, 895. [http://dx.doi.org/10.1107/S0021889806035059 doi:10.1107/S0021889806035059] | ||
| + | * Takuro Matsunaga, Takamasa Sakai, Yuki Akagi, Ung-il Chung and Mitsuhiro Shibayama [http://pubs.acs.org/doi/abs/10.1021/ma901013q SANS and SLS Studies on Tetra-Arm PEG Gels in As-Prepared and Swollen States] ''Macromolecules'' '''2009''', 42 (16), 6245–6252. [http://dx.doi.org/10.1021/ma901013q doi: 10.1021/ma901013q] | ||
| + | * R. A. Hule, R. P. Nagarkar, A. Altunbas, H. R. Ramay, M. C. Branco, J. P. Schneider and D. J. Pochan [http://pubs.rsc.org/en/Content/ArticleLanding/2008/FD/B717616C#!divAbstract Correlations between structure, material properties and bioproperties in self-assembled β-hairpin peptide hydrogels] ''Faraday Discuss.'' '''2008''', 139, 251–264. [http://dx.doi.org/10.1039/B717616C doi: 10.1039/B717616C] | ||
| + | * R. A. Hule, R. P. Nagarkar, B. Hammouda, J. P. Schneider and D. J. Pochan [http://pubs.acs.org/doi/abs/10.1021/ma9003242 Dependence of Self-Assembled Peptide Hydrogel Network Structure on Local Fibril Nanostructure] ''Macromolecules'' '''2009''', 42, 7137–7145. [http://dx.doi.org/10.1021/ma9003242 doi: 10.1021/ma9003242] | ||
| + | * B. Hammouda, F. Horkay and M. L. Becker [http://pubs.acs.org/doi/abs/10.1021/ma047960g Clustering and Solvation in Poly(acrylic acid) Polyelectrolyte Solutions] ''Macromolecules'' '''2005''', 38, 2019–2021. [http://dx.doi.org/10.1021/ma047960g doi: 10.1021/ma047960g] | ||
* Erika M. Saffer, Melissa A. Lackey, David M. Griffin, Suhasini Kishore, Gregory N. Tewb and Surita R. Bhatia [http://pubs.rsc.org/en/Content/ArticleLanding/2014/SM/c3sm52395k#!divAbstract SANS study of highly resilient poly(ethylene glycol) hydrogels] ''Soft Matter'' '''2014''', 10,1905-1916. [http://dx.doi.org/10.1039/C3SM52395K doi: 10.1039/C3SM52395K] | * Erika M. Saffer, Melissa A. Lackey, David M. Griffin, Suhasini Kishore, Gregory N. Tewb and Surita R. Bhatia [http://pubs.rsc.org/en/Content/ArticleLanding/2014/SM/c3sm52395k#!divAbstract SANS study of highly resilient poly(ethylene glycol) hydrogels] ''Soft Matter'' '''2014''', 10,1905-1916. [http://dx.doi.org/10.1039/C3SM52395K doi: 10.1039/C3SM52395K] | ||
Latest revision as of 11:25, 4 May 2016
Polymer solutions frequently exhibit some degree of clustering of the polymer chains. A more extreme case are hydrogels, where the polymer chains may be strongly-associated, or even crosslinked, into a network or mesh.
Hammouda et al. proposed the following functional form to describe scattering intensity from such systems:
where B is a constant background. The first term represents the Porod scattering from clusters, while the second term is a Lorentzian function ascribed to the scattering of the polymer chains themselves. In the context of a gel, represents the average mesh size. The parameters A, C, n, and m may be used as fitting parameters.
Kratky plot
In a Kratky plot ( vs. ), the equation becomes:
See Also
- Diffuse scattering
- Boualem Hammouda, Derek L. Ho, and Steve Kline Insight into Clustering in Poly(ethylene oxide) Solutions Macromolecules 2004, 37 (18), 6932-6937. doi: 10.1021/ma049623d
- S.R. Kline "Reduction and Analysis of SANS and USANS Data using Igor Pro", J. Appl. Cryst. 2006, 39, 6, 895. doi:10.1107/S0021889806035059
- Takuro Matsunaga, Takamasa Sakai, Yuki Akagi, Ung-il Chung and Mitsuhiro Shibayama SANS and SLS Studies on Tetra-Arm PEG Gels in As-Prepared and Swollen States Macromolecules 2009, 42 (16), 6245–6252. doi: 10.1021/ma901013q
- R. A. Hule, R. P. Nagarkar, A. Altunbas, H. R. Ramay, M. C. Branco, J. P. Schneider and D. J. Pochan Correlations between structure, material properties and bioproperties in self-assembled β-hairpin peptide hydrogels Faraday Discuss. 2008, 139, 251–264. doi: 10.1039/B717616C
- R. A. Hule, R. P. Nagarkar, B. Hammouda, J. P. Schneider and D. J. Pochan Dependence of Self-Assembled Peptide Hydrogel Network Structure on Local Fibril Nanostructure Macromolecules 2009, 42, 7137–7145. doi: 10.1021/ma9003242
- B. Hammouda, F. Horkay and M. L. Becker Clustering and Solvation in Poly(acrylic acid) Polyelectrolyte Solutions Macromolecules 2005, 38, 2019–2021. doi: 10.1021/ma047960g
- Erika M. Saffer, Melissa A. Lackey, David M. Griffin, Suhasini Kishore, Gregory N. Tewb and Surita R. Bhatia SANS study of highly resilient poly(ethylene glycol) hydrogels Soft Matter 2014, 10,1905-1916. doi: 10.1039/C3SM52395K
